[87-91-2] Diethyl L-(+)-tartrate AKSci D247
 
 
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  D247    
Diethyl L-(+)-tartrate
, 99% (GC)
 
L(+)-Diethyl L-tartrate
L-(+)-Tartaric acid diethyl ester




IDENTITY
CAS Number:[87-91-2]
MDL Number:MFCD00009143
MF:C8H14O6
MW:206.19
EINECS:201-783-3
BRN:1727145
SPECIFICATIONS & PROPERTIES
Purity:99% (GC)
Available Spectra:NMR, FT-IR, GCMS, GC
Physical Form:Colorless to light yellow clear viscous liquid
Melting Point:17°C
Boiling Point:280°C
Flash Point:93°C
Optical Rotation:+7.0° ~ +9.0° (neat)
Density:1.204-1.205
Refractive Index:1.445-1.447
Long-Term Storage:Store at room temperature
UN #:Not hazmat

REFERENCES
[1]Chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols through asymmetric Simmons-Smith reaction: Chem. Lett., 61 (1992).
[2] Chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols: J. Am. Chem. Soc., 102, 5974 (1980).
[3] Enantioselective oxidation of sulfides to sulfoxides: Org. Synth. Coll., 8, 464 (1993).
[4] Review on tartrate esters as chiral auxiliaries, such as Simmons-Smith reaction and in 1,3-dipolar cycloaddition reactions: Synlett, 1075 (2003).

GHS


Signal Word
Warning

Hazard Statements
H227

Precautionary Statements
P210; P280; P370+P378; P403+P235; P501


RELATED PRODUCTS
D247Diethyl L-(+)-tartrate
D250(-)-Diethyl D-tartrate

Current as of November 24, 2017


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CATEGORIES

 Chiral Synthesis > Tartaric Acids


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