93102-05-7 N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine, Tech. AKSci V0529
 
 
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  V0529    
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine, Tech.
, ~90%
 
N-Benzyl-1-methoxy-N-((trimethylsilyl)methyl)methanamine




IDENTITY
CAS Number:93102-05-7
MDL Number:MFCD00674005
MF:C13H23NOSi
MW:237.41
BRN:4311216
SPECIFICATIONS & PROPERTIES
Purity:~90%
Spectra:NMR, FT-IR, HPLC
Physical Form:Colorless to light yellow clear liquid
Boiling Point:76°C (0.3mmHg)
Flash Point:66°C
Density:0.928-0.936
Refractive Index:1.4890-1.4940
Long-Term Storage:Store long-term at 2-8°C
HAZARDOUS MATERIALS INFORMATION
Not hazardous material

REVIEW

 Ultrasound treatment with LiF in acetonitrile generates an azomethine ylide which undergoes 1,3-dipolar cycloaddition to olefins to give pyrrolidine derivatives in good yield: J. Org. Chem., 52, 235 (1987). Also found use in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds: J. Org. Chem., 66, 2526 (2001).

REFERENCES
[1]Padwa, Albert; Journal of Organic Chemistry 1987, V52(2), P235-44

GHS

Pictograms

Signal Word
Warning

Hazard Statements
H227; H315; H319; H335

Precautionary Statements
P280; P261; P271; P235; P235+P410; P403+P235; P411+P235; P302+P352; P332+P313; P362; P305+P351+P338; P337+P313; P403+P233; P405; P503; P501


Current as of August 12, 2020


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CATEGORIES

 Organosilicons > Organosilanes


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