93102-05-7 N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine, Tech. AKSci V0529

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V0529
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine, Tech., ~90%

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N-Benzyl-1-methoxy-N-((trimethylsilyl)methyl)methanamine

IDENTITY
CAS Number:	93102-05-7
MDL Number:	MFCD00674005
MF:	C13H23NOSi
MW:	237.41
BRN:	4311216

SPECIFICATIONS & PROPERTIES
Purity:	~90%
Spectra:	NMR, FT-IR, HPLC
Physical Form:	Colorless to light yellow clear liquid
Boiling Point:	76°C (0.3mmHg)
Flash Point:	66°C
Density:	0.928-0.936
Refractive Index:	1.4890-1.4940
Long-Term Storage:	Store long-term at 2-8°C

REVIEW
Ultrasound treatment with LiF in acetonitrile generates an azomethine ylide which undergoes 1,3-dipolar cycloaddition to olefins to give pyrrolidine derivatives in good yield: J. Org. Chem., 52, 235 (1987). Also found use in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds: J. Org. Chem., 66, 2526 (2001).

REFERENCES

[1]

Padwa, Albert; Journal of Organic Chemistry 1987, V52(2), P235-44

GHS

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