Tridemorph, Calixin, Calixine, Tridemorphe, Tridemorpn, Kalinin, Kalixin, F 220 (fungicide)
IDENTITY
CAS Number:
24602-86-6
MDL Number:
MFCD00055522
MF:
C19H39NO
MW:
297.52
EINECS:
246-347-3
SPECIFICATIONS & PROPERTIES
Min. Purity Spec:
98%
Physical Form (at 20°C):
Liquid
Boiling Point:
134°C@0.5mmHg
Long-Term Storage:
Store long-term in a cool, dry place
DOT/IATA TRANSPORT INFORMATION
Not hazardous material
REVIEW 2,6-Dimethyl-4-tridecylmorpholine is a systemic fungicide used to control Erysiphe graminis, Mycosphaerella species in bananas, and Caticum solmonicolor in tea. 2,6-Dimethyl-4-tridecylmorpholine is formulated with the fungicide carbendazim, to extend its spectrum of use in cereal disease control. It is also used with a number of other fungicides including: cyproconazole, fenbuconazole, fenpropi-morph, flusilazole, propiconazole, tebucon-azole, triadimenol. 2,6-Dimethyl-N-tridecylmorpholine was active against representative of nearly all taxonomic groups of fungi; gram-positive bacteria were also sensitive although gram-negative were not. Protein and RNA syntheses were inhibited slightly. DNA synthesis was rather strongly affected already after 2 hr. Lipid synthesis was first inhibited but later stimulated. 2,6-Dimethyl-N-tridecylmorpholine also inhibited sterol biosynthesis. The antimicrobial spectrum, the characteristic morphology of treated cells of U. maydis, the observations on cross-resistance, the alleviating effect of unsaturated lipophilic compounds, and the alterations in neutral lipid pattern suggest strong similarity of the mode of action of tridemorph with that of the known inhibitors of sterol biosynthesis.
REFERENCES
[1]
Sanne, Walter; Koenig, Karl H.; Pommer, Ernst H.; Stummeyer, Fungicides (1962), BE 614214 19620821.
N-Tridecyl-2,6-dimethylmorpholine Ger. Offen. (1971), DE 1943500 A 19710930.
[4]
Raederstorff D; Rohmer M The action of the systemic fungicides tridemorph and fenpropimorph on sterol biosynthesis by the soil amoeba Acanthamoeba polyphaga European journal of biochemistry / FEBS (1987), 164(2), 421-6.
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