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REVIEW Uused in the synthesis of highly substituted indenes via palladium-catalyzed carboannulation and indenones via a rhodium-catalyzed reaction with 2-bromophenylboronic acids.
REFERENCES
[1]
Thakur, A.; Louie, J. Advances in Nickel-Catalyzed Cycloaddition Reactions To Construct Carbocycles and Heterocycles. Acc. Chem. Res. 2015, 48 (8), 2354-2365.
[2]
Trost, B. M.; Koester, D. C.; Herron, A. N. Stereocontrolled Synthesis of Vinyl Boronates and Vinyl Silanes via Atom-Economical Ruthenium-Catalyzed Alkene-Alkyne Coupling. Angew. Chem. Int. Ed. 2015, 127 (52), 16089-16092.
[3]
Zhang D, Liu Z, Yum EK, Larock RC. Synthesis of indenes by the transition metal-mediated carboannulation of alkynes. J Org Chem. 2007 Jan 5;72(1):251-62.
[4]
Harada Y, Nakanishi J, Fujihara H, Tobisu M, Fukumoto Y, Chatani N. Rh(I)-catalyzed carbonylative cyclization reactions of alkynes with 2-bromophenylboronic acids leading to indenones. J Am Chem Soc. 2007 May 2;129(17):5766-71.
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