80149-80-0 TEOC-ONp AKSci J93300
 
 
Loading Please Wait...
  J93300    
TEOC-ONp, 95%
 
4-Nitrophenyl-2-(trimethylsilyl)ethyl carbonate
IDENTITY
CAS Number:80149-80-0
MDL Number:MFCD00042930
MF:C12H17NO5Si
MW:283.35
EINECS:279-406-7
SPECIFICATIONS & PROPERTIES
Min. Purity Spec:95%
Physical Form (at 20°C):Solid
Melting Point:35-40°C
Long-Term Storage:Store long-term at 2-8°C
DOT/IATA TRANSPORT INFORMATION
Not hazardous material

REVIEW
 It is employed as a reagent for the introduction of the TEOC-amino protecting group which can be cleaved by F-.

REFERENCES
[1]Andre Rosowsky.; Joel E. Wright. N.µ.-Alkoxycarbonylation of .alpha.,.µ.-diamino acids with 2-(trimethylsilyl)ethyl 4-nitrophenyl carbonate. J. Org. Chem. 1983, 48 (9), 1539-1541.
[2] Takamasa Iimori.; Takafumi Shibazaki.; Shiro Ikegami. A novel intramolecular decarboxylative glycosylation via mixed carbonate. Tetrahedron Lett. 1996, 37 (13),2267-2270.

GLOBALLY HARMONIZED SYSTEM (GHS)

Pictograms

Signal Word
Warning

Hazard Statements
H315; H319; H335

Precautionary Statements
P261; P264; P271; P280; P302+P352; P304+P340; P305+P351+P338; P312; P321; P332+P313; P337+P313; P362; P403+P233; P405; P501

Current as of January 27, 2023


Download SDS Request COA

⚠️
These chemical products are for research and development use only. They are not for diagnostic, therapeutic, cosmetic, or human and animal uses. They are not sold to individuals. Additional restrictions may apply.

New customers undergo an internal onboarding process. As part of this process, new customers may be asked for more information.


CATEGORIES
 Organosilicons > Protection;Organosilanes


PubChem