14221-01-3 Tetrakis(triphenylphosphine)palladium(0), packed under nitrogen AKSci J51693
 
 
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  J51693    
Tetrakis(triphenylphosphine)palladium(0), packed under nitrogen
, 95%
 
Palladium(0) tetrakis(triphenylphosphine)




IDENTITY
CAS Number:14221-01-3
MDL Number:MFCD00010012
MF:C72H60P4Pd
MW:1155.56
EINECS:238-086-9
BRN:6704828
SPECIFICATIONS & PROPERTIES
Min. Purity Spec:95%
Physical Form:Yellow to brown powder or crystals
Melting Point:100-107°C
Long-Term Storage:Store long-term at -20°C
Note:Packed under nitrogen.
DOT/IATA TRANSPORT INFORMATION
Not hazardous material

REVIEW

 A catalyst for coupling reactions such as the Heck, Suzuki, Negishi and Sonogashira cross-coupling reactions and Buckwald-Hartwig aminations (1-5). High yielding palladium-catalyzed reductive debromination of fused diporphyrins (6). A catalyst employed in arylation of sulfonamide stabilised enolates (7) and allylation of Meldrum's acids by allylic alcohols without prior activation of allylic hydroxy group (8).

REFERENCES
[1]Tetrahedron Lett. 1993, 34, 2813.
[2] J. Phys. Chem. C, 2008, 112, 10273.
[3] Adv. Synth. Catal. 2009, 351, 1727.
[4] Synthesis 2007, 1061.

GLOBALLY HARMONIZED SYSTEM (GHS)

Pictograms

Signal Word
Warning

Hazard Statements
H315; H319; H335

Precautionary Statements
P261; P264; P271; P280; P302+P352; P304+P340; P305+P351+P338; P312; P321; P332+P313; P337+P313; P362; P403+P233; P405; P501


Current as of September 21, 2021


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CATEGORIES

 Reagents > Common, Transition Metal Catalysts


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