72804-96-7 O-Diphenylphosphinylhydroxylamine AKSci B812
 
 
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  B812    
O-Diphenylphosphinylhydroxylamine
, 95% (HPLC)
 
(Aminooxy)diphenylphosphine oxide




IDENTITY
CAS Number:72804-96-7
MDL Number:MFCD12755701
MF:C12H12NO2P
MW:233.2
SPECIFICATIONS & PROPERTIES
Min. Purity Spec:95% (HPLC)
Spectra:LCMS, FT-IR, HPLC
Physical Form:White to light brown powder
Melting Point:101-110°C
Long-Term Storage:Store long-term at 2-8°C
HAZARDOUS MATERIALS INFORMATION
Not hazardous material

REVIEW

 O-Diphenylphosphinylhydroxylamine has been used to aminate imide salts, carbanions, tertiary phosphines, and thioethers. Among its advantages are direct preparation from hydroxylamine and its use in anhydrous or nonpolar solvents.

REFERENCES
[1]Harger, M. J. P. J. Chem. Soc., Perkin Trans. 1 1981, 3284.
[2] Colvin, E. W.; Kirby, G. W.; Wilson, A. C. Tetrahedron Lett. 1982, 23, 3835.
[3] Boche, G.; Bernheim, M.; Schrott, W. Tetrahedron Lett. 1982, 23, 5399.
[4] Organic Syntheses, Coll. Vol. 7, p.8 (1990); Vol. 64, p.96 (1986).

GHS

Pictograms

Signal Word
None

Hazard Statements
H315; H319; H335

Precautionary Statements
P261; P264; P271; P280; P302+P352; P304+P340; P305+P351+P338; P312; P321; P332+P313; P337+P313; P362; P403+P233; P405; P501


Current as of September 24, 2020


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CATEGORIES

 Reagents > Amination


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