80149-80-0 TEOC-ONp AKSci B417
 
 
Loading Please Wait...
  B417    
TEOC-ONp, 97% (GC)
 
4-Nitrophenyl-2-(trimethylsilyl)ethyl carbonate
IDENTITY
CAS Number:80149-80-0
MDL Number:MFCD00042930
MF:C12H17NO5Si
MW:283.35
EINECS:279-406-7
SPECIFICATIONS & PROPERTIES
Min. Purity Spec:97% (GC)
Spectra:NMR, GCMS, FT-IR, GC
Physical Form:White to off white crystalline powder
Melting Point:35-40°C
Long-Term Storage:Store long-term at 2-8°C
DOT/IATA TRANSPORT INFORMATION
Not hazardous material

REVIEW
 It is employed as a reagent for the introduction of the TEOC-amino protecting group which can be cleaved by F-.

REFERENCES
[1]Andre Rosowsky.; Joel E. Wright. N.µ.-Alkoxycarbonylation of .alpha.,.µ.-diamino acids with 2-(trimethylsilyl)ethyl 4-nitrophenyl carbonate. J. Org. Chem. 1983, 48 (9), 1539-1541.
[2] Takamasa Iimori.; Takafumi Shibazaki.; Shiro Ikegami. A novel intramolecular decarboxylative glycosylation via mixed carbonate. Tetrahedron Lett. 1996, 37 (13),2267-2270.

GLOBALLY HARMONIZED SYSTEM (GHS)

Pictograms

Signal Word
None

Hazard Statements
H315; H319; H335

Precautionary Statements
P261; P264; P271; P280; P302+P352; P304+P340; P305+P351+P338; P312; P321; P332+P313; P337+P313; P362; P403+P233; P405; P501

Current as of October 24, 2021


Download SDS

For research use only. Not for diagnostic or therapeutic use. Not for human use. AK Scientific, Inc. does not sell to individuals. If you are a first-time customer, please email for review at least two official business documents issued by your local jurisdiction, state/province, or country.


CATEGORIES
 Organosilicons > Protection;Organosilanes


PubChem