80149-80-0 TEOC-ONp AKSci B417

Loading Please Wait...

B417
TEOC-ONp, 97% (GC)

Add to Favorites

4-Nitrophenyl-2-(trimethylsilyl)ethyl carbonate

SPECIFICATIONS & PROPERTIES
Purity:	97% (GC)
Spectra:	NMR, GCMS, FT-IR, GC
Physical Form:	White to off white crystalline powder
Melting Point:	35-40°C
Long-Term Storage:	Store long-term at 2-8°C
UN #:	Not hazmat

REVIEW
It is employed as a reagent for the introduction of the TEOC-amino protecting group which can be cleaved by F-.

REFERENCES

[1]	Andre Rosowsky.; Joel E. Wright. N.μ.-Alkoxycarbonylation of .alpha.,.μ.-diamino acids with 2-(trimethylsilyl)ethyl 4-nitrophenyl carbonate. J. Org. Chem. 1983, 48 (9), 1539-1541.
[2]	Takamasa Iimori.; Takafumi Shibazaki.; Shiro Ikegami. A novel intramolecular decarboxylative glycosylation via mixed carbonate. Tetrahedron Lett. 1996, 37 (13),2267-2270.

GHS

Pictograms