1517-82-4 (1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate AKSci 2839AH
 
 
Loading Please Wait...
  2839AH    
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate
, 99% (GC)
 
(−)-(1R)-Menthyl (S)-p-toluenesulfinate




IDENTITY
CAS Number:1517-82-4
MDL Number:MFCD00010192
MF:C17H26O2S
MW:294.46
SPECIFICATIONS & PROPERTIES
Min. Purity Spec:99% (GC)
Spectra:NMR, GCMS, FT-IR, GC, Polarimetry
Physical Form:White crystalline powder
Melting Point:100-104°C
Optical Rotation:-193.2° (c=0.54 in Acetone)
Long-Term Storage:Store long-term at -20°C
HAZARDOUS MATERIALS INFORMATION
Not hazardous material

REVIEW

 It is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis, for example, metal ketimines to form enantiopure sulfinimines; p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine.

REFERENCES
[1]Asymmetric synthesis and properties of sulfinimines (thiooxime S-oxides). Davis FA, et al. The Journal of Organic Chemistry 62(8), 2555-2563, (1997)
[2] Asymmetric synthesis of the antibiotic (+)-thiamphenicol using cis-N-(p-toluenesulfinyl) aziridine 2-carboxylic acids Davis FA and Zhou P. Tetrahedron Letters 35(41), 7525-7528, (1994)

GHS

Pictograms

Signal Word
None

Hazard Statements
H315; H319; H335

Precautionary Statements
P261; P264; P271; P280; P302+P352; P304+P340; P305+P351+P338; P312; P321; P332+P313; P337+P313; P362; P403+P233; P405; P501


RELATED PRODUCTS
4007AL(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate

Current as of April 18, 2021


Download SDS

For research use only. Not for diagnostic or therapeutic use. Not for human use. AK Scientific, Inc. does not sell to individuals. If you are a first-time customer, please email for review at least two official business documents issued by your local jurisdiction, state/province, or country.



PubChem