D247 Diethyl L-(+)-tartrate - AK Scientific
 
 
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  Catalog ID # D247
Diethyl L-(+)-tartrate
, 99% (GC)
 
L(+)-Diethyl L-tartrate
L-(+)-Tartaric acid diethyl ester




IDENTITY
CAS Registry #:[87-91-2]
MDL Number:MFCD00009143
MF:C8H14O6
MW:206.19
EINECS:201-783-3
BRN:1727145
SPECIFICATIONS & PROPERTIES
Purity:99% (GC)
Available Spectra:NMR, FT-IR, GCMS, GC
Physical Form:Colorless to light yellow clear viscous liquid
Melting Point:17°C
Boiling Point:280°C
Flash Point:93°C
Optical Rotation:+7.0° ~ +9.0° (neat)
Density:1.204-1.205
Refractive Index:1.445-1.447
Long-Term Storage:Store at room temperature
Shipping:Regulated for Shipping
UN #:NA1993
Hazard Class:NONE
Packing Group:III

REFERENCES
[1]Chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols through asymmetric Simmons-Smith reaction: Chem. Lett., 61 (1992).
[2] Chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols: J. Am. Chem. Soc., 102, 5974 (1980).
[3] Enantioselective oxidation of sulfides to sulfoxides: Org. Synth. Coll., 8, 464 (1993).
[4] Review on tartrate esters as chiral auxiliaries, such as Simmons-Smith reaction and in 1,3-dipolar cycloaddition reactions: Synlett, 1075 (2003).

Risk Description(s)
R36/37/38:Irritating to eyes, respiratory system and skin

Safety Description(s)
S15:Keep away from heat.
S24/25:Avoid contact with skin and eyes.


Pricing

RELATED PRODUCTS
D247Diethyl L-(+)-tartrate
D250(-)-Diethyl D-tartrate

CURRENT AS OF: August 25, 2016

Availability
1. Backordered: Please contact us for availability.
2. All prices FOB San Francisco, USA

HazMat
HazMat shipping information is based on IATA/DOT regulations. All of the information is for reference only and subject to change without notice.

Quality
1. All products' quality is guaranteed.
2. Lot-specific spectra and CoA available on request.

Usage
AK Scientific products are intended for Research and Development usage only. The products are not to be used for other purposes, including, but not limited to, human or animal use, or as a component in, a food, drug, medical device (including in vitro diagnostic reagents), cosmetics and pesticides.

The hazards associated with this chemical have not been fully evaluated. This chemical is to be used for research and development purposes only, under the supervision of a technically qualified individual.

AK Scientific is not an EPA registered pesticidal establishment. Our products are not intended for pesticidal applications.

SDS

 D247_SDS.pdf

CATEGORIES

 Chiral Synthesis > Tartaric Acids

USEFUL LINKS

  PubChem