[36982-84-0] 2,4,6-Triisopropylbenzenesulfonyl azide, stab. with ca 10% water AKSci A848
 
 
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  Catalog ID # A848
2,4,6-Triisopropylbenzenesulfonyl azide, stab. with ca 10% water
, 98%
 



IDENTITY
CAS Number:[36982-84-0]
MDL Number:MFCD00859286
MF:C15H23N3O2S
MW:309.43
SPECIFICATIONS & PROPERTIES
Purity:98%
Physical Form:White to off-white to yellow powder, solid or crystalline powder
Melting Point:38-46°C
Flash Point:110°C
Long-Term Storage:Store long-term at 2-8°C
UN #:UN2811
Hazard Class:6.1
Packing Group:III

REVIEW

 Reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered α-diazo ketones than other methods.

REFERENCES
[1]Synthesis, 368 (1980)
[2] Tetrahedron, 43, 5677 (1987)
[3] J. Am. Chem. Soc., 102, 6626 (1980); 113, 2598 (1991)

GHS

Pictograms

Signal Word
Danger

Hazard Statements
H301

Precautionary Statements
P264; P270; P301+P310; P321; P330; P405; P501


Current as of December 3, 2016


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CATEGORIES

 Peptide Synthesis > Azides
 Reagents > Azidation

USEFUL LINKS

  PubChem