87-91-2 Diethyl L-(+)-tartrate AKSci D247
 
 
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  D247    AKSci Bulk Reagent
Diethyl L-(+)-tartrate
, 99% (GC)
 
L(+)-Diethyl L-tartrate
L-(+)-Tartaric acid diethyl ester




IDENTITY
CAS Number:87-91-2
MDL Number:MFCD00009143
MF:C8H14O6
MW:206.19
EINECS:201-783-3
BRN:1727145
SPECIFICATIONS & PROPERTIES
Min. Purity Spec:99% (GC)
Physical Form (at 20°C):Liquid
Melting Point:17°C
Boiling Point:280°C
Flash Point:93°C
Optical Rotation:+7.0° ~ +9.0° (neat)
Density:1.204-1.205
Refractive Index:1.445-1.447
Long-Term Storage:Store long-term in a cool, dry place
DOT/IATA TRANSPORT INFORMATION
Not hazardous material
Packing Group:III

REFERENCES
[1]Chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols through asymmetric Simmons-Smith reaction: Chem. Lett., 61 (1992).
[2] Chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols: J. Am. Chem. Soc., 102, 5974 (1980).
[3] Enantioselective oxidation of sulfides to sulfoxides: Org. Synth. Coll., 8, 464 (1993).
[4] Review on tartrate esters as chiral auxiliaries, such as Simmons-Smith reaction and in 1,3-dipolar cycloaddition reactions: Synlett, 1075 (2003).

GLOBALLY HARMONIZED SYSTEM (GHS)

Pictograms

Signal Word
Warning

Hazard Statements
H227; H315; H319

Precautionary Statements
P280; P302+P352; P332+P313; P362; P305+P351+P338; P337+P313; P403+P235; P503; P501


RELATED PRODUCTS
D247Diethyl L-(+)-tartrate
D250(-)-Diethyl D-tartrate

Current as of April 19, 2024


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CATEGORIES

 Chiral Synthesis > Tartaric Acids


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